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CPID

Health effects of consumer products

Monsanto Lariat Herbicide (agricultural)

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  Alachlor	015972-60-8	27.2		Yes  NY-01: California Prop. 65 Chemical NY-16: California Title 22 Chemical Exceeding MCLs CA-01-California Prop. 65 Chemicals CA-17-California Title 22 Chemicals Exceeding MCLs MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Atrazine	001912-24-9	15.5		Yes  NY-01: California Prop. 65 Chemical NY-16: California Title 22 Chemical Exceeding MCLs NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical NY-26: New York DOH MCL CA-01-California Prop. 65 Chemicals CA-17-California Title 22 Chemicals Exceeding MCLs CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Emulsifier H	000000-42-2	<10		No
  Chlorobenzene	000108-90-7	<20		Yes  NY-09: ATSDR Neurotoxicants NY-16: California Title 22 Chemical Exceeding MCLs NY-17: California Toxic Air Contaminant Chemicals (TACs) NY-18: California Priority Pollulant Chemicals in Water NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical CA-10: ATSDR Neurotoxicants CA-17-California Title 22 Chemicals Exceeding MCLs CA-18-California Toxic Air Contaminant Chemicals (TACs) CA-19-California Priority Pollulant Chemicals in Water CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  Ethylene glycol	000107-21-1	<3		Yes  NY-01: California Prop. 65 Chemical NY-11: NTP Reproductive or Developmental Toxicant NY-15: California State Water Resources Board, Drinking Water NL NY-17: California Toxic Air Contaminant Chemicals (TACs) CA-01-California Prop. 65 Chemicals CA-12-NTP Reproductive or Developmental Toxicants CA-16-California State Water Resources Board, Drinking Water NL CA-18-California Toxic Air Contaminant Chemicals (TACs) MN-01-Minnesota Toxic Free Kids, CHC OR-01: Oregon HPCCCH VT-01: Vermont State CHCC WA-01: Washington State CHCC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Alachlor	015972-60-8	240-110-8	27.2	H351 H302 H317 H410 ------- No
  Atrazine	001912-24-9	217-617-8	15.5	H317, H410, H400 P102, P260, P261, P272, P273, P280, P302+P352, P314, P321, P333+P313, P363, P391, P501 No
  Emulsifier H	000000-42-2	--	<10	-------- ------- ---- No
  Chlorobenzene	000108-90-7	203-628-5	<20	H226, H332, H411 P260, P262, P273, P403 No
  Ethylene glycol	000107-21-1	203-473-3	<3	H302, H373 ------- No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      February 01, 1995

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	N	N	N

    • Warnings

      Warning: Hazards to Humans and Domestic Animals Keep out of reach of children. WARNING! AVISO! Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.) HARMFUL IF SWALLOWED. CAUSES EYE AND SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Do not get in eyes, on skin or on clothing. Avoid breathing vapor or spray mist.

    • Acute health effects

      From MSDS Potential Adverse Health Effects: Likely Routes of Exposure: Inhalation and skin contact. Eye Contact: Contact with LARIAT® Flowable herbicide has been reported to cause eye pain, redness and tearing based on human experience. Skin Contact: LARIAT® Flowable herbicide may cause pain, redness and dry skin based on toxicity studies. Repeated contact with this material may cause allergic skin reaction in susceptible individuals. Monochlorobenzene may act on the skin and mucous membranes as a defatting agent to produce drying and redness. Ingestion: No more than slightly toxic based on toxicity studies. No significant adverse health effects are expected to develop if only small amounts (less than a mouthful) are swallowed. Coughing, choking and shortness of breath may occur if material is accidentally drawn into the lungs during swallowing or vomiting. This product contains monochlorobenzene which, if swallowed may result in central nervous system depression, headache, dizziness, fatigue, and with more severe exposures, incoordination, and unconsciousness. Inhalation: Inhalation of LARIAT® Flowable herbicide may be irritating to the respiratory tract. Prolonged or excessive inhalation of the hydrocarbons in the product may result in central nervous system depression.

    • Chronic health effects

      From MSDS Repeated contact with this material may cause allergic skin reaction in susceptible individuals. Monochlorobenzene may act on the skin and mucous membranes as a defatting agent to produce drying and redness. Prolonged or excessive inhalation of the hydrocarbons in the product may result in central nervous system depression.

    • Carcinogenicity

      From MSDS None given.

    • Handling information

      From MSDS

    • Disposal information

      From MSDS Wastes of this pesticide may cause eye and skin irritation and may be dangerous. Improper disposal of excess pesticide, spray mixtures, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of according to label use instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. Dispose of containers as follows: Plastic Jugs: Do not reuse container. Triple rinse container. Then puncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. Bulk Containers: Triple rinse emptied bulk containers. Then offer for recycling or reconditioning or dispose of in a manner approved by state and local authorities. Product which has been contaminated or is not wanted and will be discarded is classified as hazardous under the Federal Resource Conservation and Recovery Act (RCRA) and related state laws. Specific State and Federal requirements for handling and disposal will apply unless quantities are small and exemptions apply. State regulations may vary and State authorities should be consulted. Soil, water and other debris contaminated with this product may have to be treated as hazardous under RCRA depending on quantity and whether or not the waste meets the ignitability criteria (flash point less than 140 degrees F) for hazardous waste. State or Federal authorities should be contacted for appropriate handling and disposal methods.

    • First Aid

      From MSDS If in Eyes: Immediately flush with plenty of water for at least 15 minutes. Get medical attention. If on Skin: Immediately flush with plenty of water while removing contaminated clothing. Sensitized persons should avoid further contact and reuse of contaminated clothing. Get medical attention. If Swallowed: DO NOT INDUCE VOMITING. Give large quantities of water to drink. Get medical attention. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NOTE TO PHYSICIAN: Vomiting may cause aspiration pneumonia. Probable mucosal damage may contraindicate the use of gastric lavage. If Inhaled: Remove individual to fresh air. Get medical attention if breathing difficulty develops.